Product ID:DEF (SEE SUPPL)
MSDS Date:10/24/1988
FSC:NIIN:Submitter:D RV
Status Code:A
Kit Part:Y
MSDS Number: CLPBD

Emergency Phone: 814-359-3441

Info Phone: 814-359-3441

Cage: 6F718

Telephone: 814-359-3441

Cage: 6F718

PHOSPHOROTRITHIOC ACID,S,S,S-TRIBUTYL ESTER

CAS: 78-48-8

RTECS: TG5425000

Health Hazards Acute and Chronic:CHOLINESTERASE INHIBITOR. CONSTRICTED
PUPILS. CHEST PAINS.. PULMONARY EDEMA. NAUSEA. GASTROINTESTINAL
DISTURBANCES. PROFUSE SWEATING. CONVULSIONS. COMA. ATROPINE AND
2-PAM ARE ANTIDOTAL. PULMONARY EDE MA MAY REQUIRE AN OXYGEN TENT.
Effects of Overexposure:CHOLINESTERASE INHIBITOR. CONSTRICTED PUPILS.
CHEST PAINS.. PULMONARY EDEMA. NAUSEA. GASTROINTESTINAL
DISTURBANCES. PROFUSE SWEATING. CONVULSIONS. COMA. ATROPINE AND
2-PAM ARE ANTIDOTAL. PULMONARY EDE MA MAY REQUIRE AN OXYGEN TENT.

First Aid:EYE: FLUSH EYES WITH WATER FOR 15 MINUTES. SKIN: PROMPTLY
WASH WITH MILD SOAP AND LARGE VOLUMES OF WATER. INHALATION:
IMMEDIATELY MOVE TO FRESH AIR. GIVE OXYGEN IF BREATHING IS LABORED.
IF BREATHING S TOPS, GIVE ARTIFICIAL RESPIRATION. INGESTION: NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. NEVER TRY TO MAKE
AN UNCONSCIOUS PERSON VOMIT. GIVE LARGE AMOUNTS OF WATER. GIVE
SYRUP OF IPECAC. M AKE VOMIT UNTIL VOMIT IS CLEAR. IMMEDIATELY
CONTACT PHYSICIAN.

Extinguishing Media:CO2. DRY CHEMICAL, ALCOHOL FOAM.
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS WHEN
FIGHTING A CHEMICAL FIRE.
Unusual Fire/Explosion Hazard:THE FOLLOWING TOXIC VAPORS ARE FORMED
WHEN THIS MATERIAL IS HEATED TO DECOMPOSITION. OXIDES OF PHOSPHORUS
AND SULFUR, DIBUTYL DISULFIDE, BUTYL MERCAPTAN.

Spill Release Procedures:TAKE UP WITH ABSORBENT MATERIAL. VENTILATE
AREA.

Handling and Storage Precautions:STORE IN SEALED CONTAINER IN COOL, DRY
LOCATION. KEEP AWAY FROM BASES.
Other Precautions:AVOID EYE OR SKIN CONTACT.

Ventilation:USE ONLY IN WELL VENTILATED AREA.
Protective Gloves:WEAR NEOPRENE GLOVES.
Eye Protection:WEAR GOGGLES.
Supplemental Safety and Health
CONTD FROM PRODUCT ID: 44599, HERBICIDE KIT 53 LQ CONTAINING: SILVEX
METHYL ESTER, 2,4-D-METHYL ESTER,
2-(2,4,5-TRICHLOROPHENOXY)PROPIONIC ACID; 2,4-D ACID;
2,4,5-T-METHYLESTER; 2,4-DB ACID; 2,4,5-T; 2,4-DB-METHYETHER;
2,4-D-ISOOCTYLESTER; SILVEX ISOOCTYLESTER; CIPC; RAMROD; DEF;
SILVEX PGBE ESTER.SEE OTHER INFO

HCC:T5
Melt/Freeze Pt:=25.C, 77.F
Spec Gravity:1.057G/ML
Appearance and Odor:YELLOW LIQUID; MERCAPTAN ODOR

Stability Indicator/Materials to Avoid:YES
STRONG BASES
Hazardous Decomposition Products:OXIDES OF PHOSPHORUS AND SULFUR,
DIBUTYL DISULFIDE, BUTYL MERCAPTAN

Waste Disposal Methods:COMPLY WITH ALL APPLICABLE FEDERAL, STATE AND
LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:FORMALDEHYDE HAS HIGH ACUTE TOXICITY TO AQUATIC LIFE.
INSUFFICIENT DATA ARE AVAILABLE TO EVALUATE OR PREDICT THE
SHORT-TERM EFFECTS OF FORMALDEHYDE TO PLANTS, BIRDS, OR LAND
ANIMALS. CHRONIC TOXIC EFF ECTS MAY INCLUDE SHORTENED LIFESPAN,
REPRODUCTIVE PROBLEMS, LOWER FERTILITY, AND CHANGES IN APPEARANCE
OR BEHAVIOR. CHRONIC EFFECTS CAN BE SEEN LONG AFTER FIRST EXPOSURE
TO A TOXIC CHEMICAL. (AQUIRE D ATABASE, ERRL-DULUTH, U.S.EPA.,
PHYTOTOX).

Transport Information:PROPER SHIPPING NAME: FORMIC ACID SOLUTIONS.
HAZARD CLASS OR DIVISION: 8. IDENTIFICATION NUMBERS: UN1779.
PACKING GROUP: II. LABEL(S) REQUIRED (IF NOT EXCEPTED): CORROSIVE,
EXCEPTION 1 LITER OR LESS ( LTD. QTY.). SPECIAL PROVISIONS:
PACKAGING AUTHORIZATIONS: EXCEPTIONS: 173.154. NON-BULK PACKAGING:
173.202. QUANTITY LIMITATIONS: PASSENGER AIRCRAFT OR RAILCAR: 1 L.
CARGO AIRCRAFT ONLY: 30 L.

SARA Title III Information:SECTION 302 & 304: EXTREMELY HAZARDOUS
SUBSTANCE LIST( 40 CFR 355) - LISTED. SECTION 311: HAZARD
CATEGORIZATION (40 CFR 370) - ACUTE, CHRONIC, AND FIRE. SECTION
313: TOXIC CHEMICALS LISTING (40 CFR 37 2.65) - LISTED AS A TOXIC
CHEMICAL.
Federal Regulatory Information:CERCLA (COMPREHENSIVE ENVIRONMENTAL
RESPONSE, COMPENSATION AND LIABILITY ACT): SECTION 102(A) HAZARDOUS
SUBSTANCES (40 CFR 302.4)- LISTED. REPORTABLE QUANTITY - 1,000
POUNDS. SECTION 101 (14) REPORTAB LE QUANTITY: 1,000 LBS. RCRA
(RESOURCE CONSERVATION AND RECOVERY ACT.): 40 CFR 261.33 HAZARDOUS
WASTE NUMBER: U122. TSCA (TOXIC SUBSTANCE CONTROL ACT)- LISTED.
NFPA: HEALTH-3, FIRE-2, REACTIVITY-0.
State Regulatory Information:NJ-RTK (NEW JERSEY - STATE RIGHT TO KNOW)
ENVIRONMENTAL HAZARDOUS SUBSTANCE LIST: LISTED, SUBSTANCE # 0946.
OVEREXPOSURE (CONTD): VISUAL IMPAIRMENT, BLINDNESS & OTHER SYSTEMIC
EFFECTS. REPEATED EXPOSU RE INCREASES CANCER RISK, CAN ALSO LEAD TO
CONJUCTIVITIS, DERMATITIS, METABOLIC ACIDOSIS, 2ND DEGREE BURNS,
NUMBNESS, PERSISTENT ITCHING RASH, HEADACHES, STOMACH RASHES,
SERIOUS RESP IMPAIRMENT, KIDNE Y INJURY & PULMONARY SENSITIZATION.